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Polymerization Isomerism in Co-M (M = Cu, Ag, Au) Carbonyl Clusters: Synthesis, Structures and Computational Investigation

The reaction of [Co(CO)(4)](−) (1) with M(I) compounds (M = Cu, Ag, Au) was reinvestigated unraveling an unprecedented case of polymerization isomerism. Thus, as previously reported, the trinuclear clusters [M{Co(CO)(4)}(2)](−) (M = Cu, 2; Ag, 3; Au, 4) were obtained by reacting 1 with M(I) in a 2:1...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Veröffentlicht in:Molecules
Hauptverfasser: Cesari, Cristiana, Berti, Beatrice, Calcagno, Francesco, Femoni, Cristina, Garavelli, Marco, Iapalucci, Maria Carmela, Rivalta, Ivan, Zacchini, Stefano
Format: Artigo
Sprache:Inglês
Veröffentlicht: MDPI 2021
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7998641/
https://ncbi.nlm.nih.gov/pubmed/33799629
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules26061529
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