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Phase-Separating Binary Polymer Mixtures: The Degeneracy of the Virial Coefficients and Their Extraction from Phase Diagrams

[Image: see text] The Edmond–Ogston model for phase separation in binary polymer mixtures is based on a truncated virial expansion of the Helmholtz free energy up to the second-order terms in the concentration of the polymers. The second virial coefficients (B(11), B(12), B(22)) are the three parame...

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Detalhes bibliográficos
Publicado no:ACS Omega
Main Authors: Bot, Arjen, Dewi, Belinda P. C., Venema, Paul
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2021
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7992149/
https://ncbi.nlm.nih.gov/pubmed/33778298
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.1c00450
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