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Tetraimido Sulfuric Acid H(2)S(NtBu)(4)—Valence Isoelectronic to H(2)SO(4)

The valence isoelectronic imido analog H(2)S(NtBu)(4) (1) of sulfuric acid H(2)SO(4) was synthesized, isolated, and characterized by NMR spectroscopy and high‐resolution X‐ray charge density analysis. The latter reveals strongly polarized S(δ+)−N(δ−) bonds with virtually no double bond character. Th...

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Publicado en:Angew Chem Int Ed Engl
Autores principales: Jung, Jochen, Münch, Annika, Herbst‐Irmer, Regine, Stalke, Dietmar
Formato: Artigo
Lenguaje:Inglês
Publicado: John Wiley and Sons Inc. 2021
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC7986191/
https://ncbi.nlm.nih.gov/pubmed/33480147
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202014426
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