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Tetraimido Sulfuric Acid H(2)S(NtBu)(4)—Valence Isoelectronic to H(2)SO(4)

The valence isoelectronic imido analog H(2)S(NtBu)(4) (1) of sulfuric acid H(2)SO(4) was synthesized, isolated, and characterized by NMR spectroscopy and high‐resolution X‐ray charge density analysis. The latter reveals strongly polarized S(δ+)−N(δ−) bonds with virtually no double bond character. Th...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Jung, Jochen, Münch, Annika, Herbst‐Irmer, Regine, Stalke, Dietmar
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2021
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7986191/
https://ncbi.nlm.nih.gov/pubmed/33480147
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202014426
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