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Kinetic description of site ensembles on catalytic surfaces
We demonstrate that the Langmuir–Hinshelwood formalism is an incomplete kinetic description and, in particular, that the Hinshelwood assumption (i.e., that adsorbates are randomly distributed on the surface) is inappropriate even in catalytic reactions as simple as A + A → A(2). The Hinshelwood assu...
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| Published in: | Proc Natl Acad Sci U S A |
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| Main Authors: | , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
National Academy of Sciences
2021
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7923573/ https://ncbi.nlm.nih.gov/pubmed/33608461 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.2019055118 |
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