Tuning π-Acceptor/σ-Donor Ratio of the 2-Isocyanoazulene Ligand: Non-Fluorinated Rival of Pentafluorophenyl Isocyanide and Trifluorovinyl Isocyanide Discovered

Isocyanoazulenes (CNAz) constitute a relatively new class of isocyanoarenes that offers rich structural and electronic diversification of the organic isocyanide ligand platform. This article considers a series of 2-isocyano-1,3-X(2)-azulene ligands (X = H, Me, CO(2)Et, Br, and CN) and the correspond...

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Udgivet i:Molecules
Main Authors: Hart, Mason D., Meyers, John J., Wood, Zachary A., Nakakita, Toshinori, Applegate, Jason C., Erickson, Nathan R., Gerasimchuk, Nikolay N., Barybin, Mikhail V.
Format: Artigo
Sprog:Inglês
Udgivet: MDPI 2021
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7918097/
https://ncbi.nlm.nih.gov/pubmed/33673291
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules26040981
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