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Cavity frequency-dependent theory for vibrational polariton chemistry

Recent experiments demonstrate the control of chemical reactivities by coupling molecules inside an optical microcavity. In contrast, transition state theory predicts no change of the reaction barrier height during this process. Here, we present a theoretical explanation of the cavity modification o...

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Foilsithe in:Nat Commun
Main Authors: Li, Xinyang, Mandal, Arkajit, Huo, Pengfei
Formáid: Artigo
Teanga:Inglês
Foilsithe: Nature Publishing Group UK 2021
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7910560/
https://ncbi.nlm.nih.gov/pubmed/33637720
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-021-21610-9
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