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Olefin-Supported Cationic Copper Catalysts for Photochemical Synthesis of Structurally Complex Cyclobutanes

The sole method available for the photocycloaddition of unconjugated aliphatic alkenes is the Cu-catalyzed Salomon-Kochi reaction. The [Cu(OTf)](2)•benzene catalyst that has been standard in this reaction for many decades, however, is air-sensitive, prone to photodecomposition, and is poorly reactiv...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Gravatt, Christopher S., Melecio-Zambrano, Luis, Yoon, Tehshik P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7902453/
https://ncbi.nlm.nih.gov/pubmed/33179414
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202013067
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