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Highly Deformed o‐Carborane Functionalised Non‐linear Polycyclic Aromatics with Exceptionally Long C−C Bonds

The effect of substituting o‐carborane into the most sterically hindered positions of phenanthrene and benzo(k)tetraphene is reported. Synthesised via a Bull–Hutchings–Quayle benzannulation, the crystal structures of these non‐linear acenes exhibited the highest aromatic deformation parameters obser...

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Pubblicato in:Chemistry
Autori principali: Marsh, Adam V., Little, Mark, Cheetham, Nathan J., Dyson, Matthew J., Bidwell, Matthew, White, Andrew J. P., Warriner, Colin N., Swain, Anthony C., McCulloch, Iain, Stavrinou, Paul N., Heeney, Martin
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7898797/
https://ncbi.nlm.nih.gov/pubmed/33044792
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202004517
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