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Not‐So‐Innocent Anions Determine the Mechanism of Cationic Alkylators
Alkylating reagents based on thioimidazolium ionic liquids were synthesized and the influence of the anion on the alkylation reaction mechanism explored in detail using both experimental and computational methods. Thioimidazolium cations transfer alkyl substituents to nucleophiles, however the react...
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| Publicado no: | Chemistry |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2021
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7898791/ https://ncbi.nlm.nih.gov/pubmed/33137244 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202004208 |
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