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Carbenaporphyrins: No Longer Missing Ligands in N‐Heterocyclic Carbene Chemistry
The synthesis of an NHC‐containing porphyrinoid ligand is presented. The formally antiaromatic 20 πe(−) macrocyclic framework can be obtained via a 1,3‐dipolar cycloaddition (“click‐reaction”) to form two triazole moieties which were alkylated to the respective triazolium macrocycle. Deprotonation o...
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| Vydáno v: | Angew Chem Int Ed Engl |
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| Hlavní autoři: | , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
John Wiley and Sons Inc.
2020
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7898644/ https://ncbi.nlm.nih.gov/pubmed/33078891 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202013434 |
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