Probing Local Electrostatics of Glycine in Aqueous Solution by THz Spectroscopy

Based upon precise terahertz (THz) measurements of the solvated amino acid glycine and accompanying ab‐initio molecular‐dynamics simulations, we show that the N‐C‐C‐O open/close mode at 315 cm(−1) serves as a sensitive, label‐free probe for the local protonation of the amide group. Experimentally, w...

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Detaylı Bibliyografya
Yayımlandı:Angew Chem Int Ed Engl
Asıl Yazarlar: Sebastiani, Federico, Ma, Chun Yu, Funke, Sarah, Bäumer, Alexander, Decka, Dominique, Hoberg, Claudius, Esser, Alexander, Forbert, Harald, Schwaab, Gerhard, Marx, Dominik, Havenith, Martina
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: John Wiley and Sons Inc. 2020
Konular:
Research Articles
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC7898531/
https://ncbi.nlm.nih.gov/pubmed/33156972
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202014133
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