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DFT and IsoStar Analyses to Assess the Utility of σ‐ and π‐Hole Interactions for Crystal Engineering

The interpretation of 36 charge neutral ‘contact pairs’ from the IsoStar database was supported by DFT calculations of model molecules 1–12, and bimolecular adducts thereof. The ‘central groups’ are σ‐hole donors (H(2)O and aromatic C−I), π‐hole donors (R−C(O)Me, R−NO(2) and R−C(6)F(5)) and for comp...

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Dettagli Bibliografici
Pubblicato in:Chemphyschem
Autore principale: Mooibroek, Tiddo Jonathan
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7898519/
https://ncbi.nlm.nih.gov/pubmed/33241585
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cphc.202000927
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