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Enantioselective, Visible Light Mediated Aza Paternò–Büchi Reactions of Quinoxalinones

3‐Substituted quinoxalin‐2(1H)‐ones and various aryl‐substituted or tethered olefins underwent an enantioselective, inter‐ or intramolecular aza Paternò–Büchi reaction upon irradiation at λ=420 nm in the presence of a chiral sensitizer (10 mol %). For the intermolecular reaction with 1‐arylethenes a...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Li, Xinyao, Großkopf, Johannes, Jandl, Christian, Bach, Thorsten
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2020
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7898282/
https://ncbi.nlm.nih.gov/pubmed/33084097
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202013276
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