Approaching a “Naked” Boryl Anion: Amide Metathesis as a Route to Calcium, Strontium, and Potassium Boryl Complexes

Amide metathesis has been used to generate the first structurally characterized boryl complexes of calcium and strontium, {(Me(3)Si)(2)N}M{B(NDippCH)(2)}(thf)(n) (M=Ca, n=2; M=Sr, n=3), through the reactions of the corresponding bis(amides), M{N(SiMe(3))(2)}(2)(thf)(2), with (thf)(2)Li‐ {B(NDippCH)(...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Protchenko, Andrey V., Vasko, Petra, Fuentes, M. Ángeles, Hicks, Jamie, Vidovic, Dragoslav, Aldridge, Simon
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7894291/
https://ncbi.nlm.nih.gov/pubmed/33026153
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202011839
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