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Vibrational heat-bath configuration interaction

We introduce vibrational heat-bath configuration interaction (VHCI) as an accurate and efficient method for calculating vibrational eigenstates of anharmonic systems. Inspired by its origin in electronic structure theory, VHCI is a selected CI approach that uses a simple criterion to identify import...

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Bibliographic Details
Published in:J Chem Phys
Main Authors: Fetherolf, Jonathan H., Berkelbach, Timothy C.
Format: Artigo
Language:Inglês
Published: AIP Publishing LLC 2021
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7889291/
https://ncbi.nlm.nih.gov/pubmed/33607897
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/5.0035454
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