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Potassium Trimethylsilanolate Enables Rapid, Homogeneous Suzuki–Miyaura Cross-Coupling of Boronic Esters

Herein, a mild and operationally simple method for the Suzuki–Miyaura cross-coupling of boronic esters is described. Central to this advance is the use of the organic-soluble base, potassium trimethylsilanolate, which allows for a homogeneous, anhydrous cross-coupling. The coupling proceeds at a rap...

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Publicat a:ACS Catal
Autors principals: Delaney, Connor P., Kassel, Vincent M., Denmark, Scott E.
Format: Artigo
Idioma:Inglês
Publicat: 2019
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7880502/
https://ncbi.nlm.nih.gov/pubmed/33585070
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.9b04353
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