Microsecond Photoluminescence and Photoreactivity of a Metal-Centered Excited State in a Hexacarbene–Co(III) Complex

[Image: see text] The photofunctionality of the cobalt–hexacarbene complex [Co(III)(PhB(MeIm)(3))(2)](+) (PhB(MeIm)(3) = tris(3-methylimidazolin-2-ylidene)(phenyl)borate) has been investigated by time-resolved optical spectroscopy. The complex displays a weak (Φ ∼ 10(–4)) but remarkably long-lived (...

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Publicat a:J Am Chem Soc
Autors principals: Kaufhold, Simon, Rosemann, Nils W., Chábera, Pavel, Lindh, Linnea, Bolaño Losada, Iria, Uhlig, Jens, Pascher, Torbjörn, Strand, Daniel, Wärnmark, Kenneth, Yartsev, Arkady, Persson, Petter
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2021
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7877722/
https://ncbi.nlm.nih.gov/pubmed/33449685
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c12151
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