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Tuning the Thermal Stability and Photoisomerization of Azoheteroarenes through Macrocycle Strain

Azobenzene and its derivatives are one of the most widespread molecular scaffolds used in a range of modern applications, as well as in fundamental research. After photoexcitation, azo‐based photoswitches revert back to the most stable isomer on a timescale ([Formula: see text] ) that determines the...

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發表在:Chemistry
Main Authors: Vela, Sergi, Scheidegger, Alan, Fabregat, Raimon, Corminboeuf, Clémence
格式: Artigo
語言:Inglês
出版: John Wiley and Sons Inc. 2020
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC7839710/
https://ncbi.nlm.nih.gov/pubmed/32991023
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003926
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