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Iodonium Cation‐Pool Electrolysis for the Three‐Component Synthesis of 1,3‐Oxazoles

The synthesis of 1,3‐oxazoles from symmetrical and unsymmetrical alkynes was realized by an iodonium cation‐pool electrolysis of I(2) in acetonitrile with a well‐defined water content. Mechanistic investigations suggest that the alkyne reacts with the acetonitrile‐stabilized I(+) ions, followed by a...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Sattler, Lars E., Hilt, Gerhard
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7839530/
https://ncbi.nlm.nih.gov/pubmed/33270278
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202004140
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