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Diterpene Biosynthesis in Catenulispora acidiphila: On the Mechanism of Catenul‐14‐en‐6‐ol Synthase

A new diterpene synthase from the actinomycete Catenulispora acidiphila was identified and the structures of its products were elucidated, including the absolute configurations by an enantioselective deuteration approach. The mechanism of the cationic terpene cyclisation cascade was deeply studied t...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Li, Geng, Guo, Yue‐Wei, Dickschat, Jeroen S.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7839432/
https://ncbi.nlm.nih.gov/pubmed/33169911
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202014180
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