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Thermodynamics of interfaces extended to nanoscales by introducing integral and differential surface tensions

As a system shrinks down in size, more and more molecules are found in its surface region, so surface contribution becomes a large or even a dominant part of its thermodynamic potentials. Surface tension is a venerable scientific concept; Gibbs defined it as the excess of grand potential of an inhom...

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Vydáno v:Proc Natl Acad Sci U S A
Hlavní autor: Dong, W.
Médium: Artigo
Jazyk:Inglês
Vydáno: National Academy of Sciences 2021
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7826379/
https://ncbi.nlm.nih.gov/pubmed/33452136
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.2019873118
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