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Photoredox chemistry in the synthesis of 2-aminoazoles implicated in prebiotic nucleic acid synthesis

Prebiotically plausible ferrocyanide–ferricyanide photoredox cycling oxidatively converts thiourea to cyanamide, whilst HCN is reductively homologated to intermediates which either react directly with the cyanamide giving 2-aminoazoles, or have the potential to do so upon loss of HCN from the system...

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Detalhes bibliográficos
Publicado no:Chem Commun (Camb)
Main Authors: Liu, Ziwei, Wu, Long-Fei, Bond, Andrew D., Sutherland, John D.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2020
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7808312/
https://ncbi.nlm.nih.gov/pubmed/33151212
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0cc05752e
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