Formation of Defect-Dicubane-Type Ni(II)(2)Ln(III)(2) (Ln = Tb, Er) Clusters: Crystal Structures and Modeling of the Magnetic Properties

[Image: see text] In the field of molecular nanoclusters, cubane and defect-dicubane, or butterfly structures, are typical examples of tetranuclear metal core architectures. In this work, a halogenated and anionic Schiff-base ligand (L(2–)) is utilized as it is predisposed to chelate within a cluste...

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Publié dans:ACS Omega
Auteurs principaux: You, Zhonglu, Prsa, Krunoslav, Mutschler, Julius, Herringer, Susan N., Wang, Jiaqi, Luo, Yingying, Zheng, Boyang, Decurtins, Silvio, Krämer, Karl W., Waldmann, Oliver, Liu, Shi-Xia
Format: Artigo
Langue:Inglês
Publié: American Chemical Society 2020
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7807793/
https://ncbi.nlm.nih.gov/pubmed/33458500
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.0c04930
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