En Route to a Chiral Melanin: The Dynamic “From-Imprinted-to-Template” Supramolecular Role of Porphyrin Hetero-Aggregates During the Oxidative Polymerization of L-DOPA

Chiral porphyrin hetero-aggregates, produced from meso-tetrakis(4-N-methylpyridyl) porphyrin H(2)T4 and copper(II) meso-tetrakis(4-sulfonatophenyl)porphyrin CuTPPS by an imprinting effect in the presence of L-3,4-dihydroxyphenylalanine (L-DOPA), are shown herein to serve as templates for the generat...

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Detalhes bibliográficos
Publicado no:Front Chem
Main Authors: Gaeta, Massimiliano, Randazzo, Rosalba, Villari, Valentina, Micali, Norberto, Pezzella, Alessandro, Purrello, Roberto, d'Ischia, Marco, D'Urso, Alessandro
Formato: Artigo
Idioma:Inglês
Publicado em: Frontiers Media S.A. 2020
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7779627/
https://ncbi.nlm.nih.gov/pubmed/33409269
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3389/fchem.2020.616961
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