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Photochemically Induced Ring Opening of Spirocyclopropyl Oxindoles: Evidence for a Triplet 1,3‐Diradical Intermediate and Deracemization by a Chiral Sensitizer
The photochemical deracemization of spiro[cyclopropane‐1,3′‐indolin]‐2′‐ones (spirocyclopropyl oxindoles) was studied. The corresponding 2,2‐dichloro compound is configurationally labile upon direct irradiation at λ=350 nm and upon irradiation at λ=405 nm in the presence of achiral thioxanthen‐9‐one...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7756555/ https://ncbi.nlm.nih.gov/pubmed/32757341 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202008384 |
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