A Mechanochemical Reaction Cascade for Controlling Load‐Strengthening of a Mechanochromic Polymer

We demonstrate an intermolecular reaction cascade to control the force which triggers crosslinking of a mechanochromic polymer of spirothiopyran (STP). Mechanochromism arises from rapid reversible force‐sensitive isomerization of STP to a merocyanine, which reacts rapidly with activated C=C bonds. T...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Pan, Yifei, Zhang, Huan, Xu, Piaoxue, Tian, Yancong, Wang, Chenxu, Xiang, Shishuai, Boulatov, Roman, Weng, Wengui
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2020
Soggetti:
Communications
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756483/
https://ncbi.nlm.nih.gov/pubmed/32827332
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202010043
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