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Synthesis‐Controlled Polymorphism and Optical Properties of Phyllosilicate‐Analogous Borosulfates M[B(2)(SO(4))(4)] (M=Mg, Co)

Increased synthetic control in borosulfate chemistry leads to the access of various new compounds. Herein, the polymorphism of phyllosilicate‐analogous borosulfates is unraveled by adjusting the oleum (65 % SO(3)) content. The new polymorphs β‐Mg[B(2)(SO(4))(4)] and α‐Co[B(2)(SO(4))(4)] both consist...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Netzsch, Philip, Pielnhofer, Florian, Glaum, Robert, Höppe, Henning A.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756226/
https://ncbi.nlm.nih.gov/pubmed/32744744
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003214
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