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Density Functional Theory for Molecule–Metal Surface Reactions: When Does the Generalized Gradient Approximation Get It Right, and What to Do If It Does Not

[Image: see text] While density functional theory (DFT) is perhaps the most used electronic structure theory in chemistry, many of its practical aspects remain poorly understood. For instance, DFT at the generalized gradient approximation (GGA) tends to fail miserably at describing gas-phase reactio...

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Publicat a:J Phys Chem Lett
Autors principals: Gerrits, Nick, Smeets, Egidius W. F., Vuckovic, Stefan, Powell, Andrew D., Doblhoff-Dier, Katharina, Kroes, Geert-Jan
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2020
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7751010/
https://ncbi.nlm.nih.gov/pubmed/33295770
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpclett.0c02452
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