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Metal-free synthesis of biarenes via photoextrusion in di(tri)aryl phosphates

A metal-free route for the synthesis of biarenes has been developed. The approach is based on the photoextrusion of a phosphate moiety occurring upon irradiation of biaryl- and triaryl phosphates. The reaction involves an exciplex as the intermediate and it is especially suitable for the preparation...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Qrareya, Hisham, Meazza, Lorenzo, Protti, Stefano, Fagnoni, Maurizio
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7736689/
https://ncbi.nlm.nih.gov/pubmed/33363669
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.16.250
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