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Synthetic, Mechanistic and Biological Interrogation of Ginkgo biloba Chemical Space en route to (−)-Bilobalide
Here we interrogate the structurally dense (1.63 mcbits/Å(3)) GABA(A) receptor antagonist bilobalide, intermediates en route to its synthesis and related mechanistic questions. (13)C isotope labeling identifies an unexpected bromine migration en route to an α-selective, catalytic asymmetric Reformat...
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| Publicado no: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7727090/ https://ncbi.nlm.nih.gov/pubmed/32991152 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c08231 |
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