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Visible-light photoredox-catalyzed C–O bond cleavage of diaryl ethers by acridinium photocatalysts at room temperature

Cleavage of C–O bonds in lignin can afford the renewable aryl sources for fine chemicals. However, the high bond energies of these C–O bonds, especially the 4-O-5-type diaryl ether C–O bonds (~314 kJ/mol) make the cleavage very challenging. Here, we report visible-light photoredox-catalyzed C–O bond...

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Publicat a:Nat Commun
Autors principals: Tan, Fang-Fang, He, Xiao-Ya, Tian, Wan-Fa, Li, Yang
Format: Artigo
Idioma:Inglês
Publicat: Nature Publishing Group UK 2020
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7705023/
https://ncbi.nlm.nih.gov/pubmed/33257656
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-020-19944-x
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