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Acyclic Cucurbit[n]uril Type Receptors: Aromatic Wall Extension Enhances Binding Affinity, Delivers Helical Chirality, and Enables Fluorescence Sensing
We report the linear extension from M1 to M2 to anthracene walled M3 which adopts a helical conformation (x-ray) to avoid unfavorable interactions between sidewalls. M3 is water soluble (≈ 30 mM) and displays enhanced optical properties (ε = 1.28 × 10(5) M(−1) cm(−1), λ(max) = 370 nm) relative to M2...
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| Udgivet i: | Chemistry |
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| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2020
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7704778/ https://ncbi.nlm.nih.gov/pubmed/32658342 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202002874 |
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