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Hydrogenation and electrocatalytic reduction of carbon dioxide to formate with a single Co catalyst

A cobalt(I) complex is shown to be capable of both electrocatalytic reduction and hydrogenation of CO(2) to formate. Several proposed intermediates are characterized and thus form the basis for a proposed mechanism that allows for the dual reactivity: reduction of CO(2) via H(2) addition, and H(+)/e...

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Detalhes bibliográficos
Publicado no:Chem Commun (Camb)
Main Authors: Wang, Fang, Cannon, Austin, Bhattacharya, Moumita, Baumgarten, Robert, Vanderlinden, Ryan T., Saouma, Caroline T.
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7703687/
https://ncbi.nlm.nih.gov/pubmed/33001067
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0cc04310a
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