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On the Origin of the Promoting Effect Exerted by Magnesium in the ZnCl(2)-Catalyzed Synthesis of N,N-Diisopropylethylamine
[Image: see text] The reaction of magnesium or zinc amides with alkyl or benzyl halides is an attractive approach to make C–N bonds, especially for electron-poor organic halides. The magnesium-promoted preparation of hindered non-nucleophilic amine (N,N-diisopropylethylamine) from ethyl chloride and...
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| Publicado no: | ACS Omega |
|---|---|
| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American
Chemical Society
2020
|
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7689953/ https://ncbi.nlm.nih.gov/pubmed/33251426 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.0c04188 |
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