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Concise Access to the Skeleton of Protoilludane Sesquiterpenes through a Photochemical Reaction Cascade: Total Synthesis of Atlanticone C

In a single photochemical operation (λ≥350 nm) an easily accessible indanone derivative was converted into a structurally complex precursor of the protoilludane sesquiterpenes. The product (60 % yield) contains all 15 carbon atoms of the skeleton in the required connectivity and was transformed into...

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Bibliografski detalji
Izdano u:Angew Chem Int Ed Engl
Glavni autori: Zech, Andreas, Jandl, Christian, Bach, Thorsten
Format: Artigo
Jezik:Inglês
Izdano: John Wiley and Sons Inc. 2019
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7687024/
https://ncbi.nlm.nih.gov/pubmed/31478314
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201908619
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