Stable Boron Dithiolene Radicals

While low-temperature (−78 °C) reaction of the lithium dithiolene radical (1(•)) with boron bromide gives the dibromoboron dithiolene radical (2(•)), the parallel reaction of 1(•) with (C(6)H(11))(2)BCl (0 °C) affords the dicyclohexylboron dithiolene radical (3(•)). Radicals 2(•) and 3(•) are charac...

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Publicado en:Angew Chem Int Ed Engl
Main Authors: Wang, Yuzhong, Xie, Yaoming, Wei, Pingrong, Blair, Soshawn A., Cui, Dongtao, Johnson, Michael K., Schaefer, Henry F., Robinson, Gregory H.
Formato: Artigo
Idioma:Inglês
Publicado: 2018
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC7679077/
https://ncbi.nlm.nih.gov/pubmed/29756257
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201804298
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