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Catalytic Activation of N(2)O at a Low-Valent Bismuth Redox Platform

[Image: see text] Herein we present the catalytic activation of N(2)O at a Bi(I)⇄Bi(III) redox platform. The activation of such a kinetically inert molecule was achieved by the use of bismuthinidene catalysts, aided by HBpin as reducing agent. The protocol features remarkably mild conditions (25 °C,...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Pang, Yue, Leutzsch, Markus, Nöthling, Nils, Cornella, Josep
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2020
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7677929/
https://ncbi.nlm.nih.gov/pubmed/33146996
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c10092
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