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Tuning the Binding Strength of Even and Uneven Hydrogen-Bonded Arrays with Remote Substituents

[Image: see text] We investigated the tunability of hydrogen bond strength by altering the charge accumulation around the frontier atoms with remote substituents. For pyridine···H(2)O with NH(2) and CN substituted at different positions on pyridine, we find that the electron-withdrawing CN group dec...

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Detalhes bibliográficos
Publicado no:J Phys Chem A
Main Authors: van der Lubbe, Stephanie C. C., Haim, Anissa, van Heesch, Thor, Fonseca Guerra, Célia
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2020
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7667637/
https://ncbi.nlm.nih.gov/pubmed/33054218
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpca.0c07815
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