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Exploring the Limits of Dative Boratrane Bonding: Iron as a Strong Lewis Base in Low-Valent Non-Heme Iron-Nitrosyl Complexes
We previously reported the synthesis and preliminary characterization of a unique series of low-spin (ls) {FeNO}(8−10) complexes supported by an ambiphilic trisphosphineborane ligand, [Fe(TPB)(NO)](+/0/−). Herein, we use advanced spectroscopic techniques and density functional theory (DFT) calculati...
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| Pubblicato in: | Inorg Chem |
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| Autori principali: | , , , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2020
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7640944/ https://ncbi.nlm.nih.gov/pubmed/32989992 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.0c01686 |
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