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Photophysical and Chiroptical Properties of the Enantiomers of N,N′-Bis(1-phenylpropyl)-2,6-pyridinecarboxamide and their Chiral 9-Coordinate Ln(3+) Complexes

The R,R and S,S enantiomers of N,N′-bis(1-phenylpropyl)-2,6-pyridinedicarboxamide, L(Et), react with Ln(3+) ions (Ln = La, Eu, Gd, and Tb) to give stable [Ln((R,R)- and (S,S)-L(Et))(3)](3+) in anhydrous acetonitrile solution, as evidenced by various spectroscopic measurements, including NMR and lumi...

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Detalhes bibliográficos
Publicado no:Eur J Inorg Chem
Main Authors: Chang, Victoria Y., Calvinho, Karin U. D., Tovar, Roberto C., Johnson, Victoria A., Straus, Daniel A., Muller, Gilles
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7640761/
https://ncbi.nlm.nih.gov/pubmed/33162787
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.202000606
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