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Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Acyclic α-N-Pyrrolyl/Indolyl Ketones.

The synthesis of fully substituted α-N-pyrrolyl and indolyl ketones via enantioselective palladium-catalyzed allylic alkylation is described. The acyclic ketones are alkylated in high yields and enantioselectivities through the use of an electron-deficient phosphinooxazoline ligand, furnishing a hig...

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Détails bibliographiques
Publié dans:Org Lett
Auteurs principaux: Lavernhe, Remi, Alexy, Eric J., Zhang, Haiming, Stoltz, Brian M.
Format: Artigo
Langue:Inglês
Publié: 2020
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7608871/
https://ncbi.nlm.nih.gov/pubmed/32422045
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c01303
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