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Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Acyclic α-N-Pyrrolyl/Indolyl Ketones.
The synthesis of fully substituted α-N-pyrrolyl and indolyl ketones via enantioselective palladium-catalyzed allylic alkylation is described. The acyclic ketones are alkylated in high yields and enantioselectivities through the use of an electron-deficient phosphinooxazoline ligand, furnishing a hig...
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| Publicado en: | Org Lett |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2020
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7608871/ https://ncbi.nlm.nih.gov/pubmed/32422045 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c01303 |
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