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Synthesis of an aminooxy derivative of the GM3 antigen and its application in oxime ligation
The anomeric aminooxy GM3 trisaccharide cancer antigen (Neu5Acα2,3Galβ1,4Glcβ-ONH(2)) has been chemically synthesized using a linear glycosylation approach. The key step involves a highly α(2,3)-stereoselective sialylation to a galactose acceptor. The Neu5Acα2,3Gal intermediate was functionalized as...
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| Publicado no: | J Org Chem |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7606269/ https://ncbi.nlm.nih.gov/pubmed/32320231 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.0c00320 |
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