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How Many Pnicogen Bonds can be Formed to a Central Atom Simultaneously?

[Image: see text] A central ZF(3) molecule (Z = P, As, Sb, Bi) is allowed to interact with a number of nucleophiles exemplified by NCH, NH(3), and NC(–) anion. The Z···N pnicogen bond (ZB) to a single base grows stronger for heavier Z atom: P < A < Sb < Bi and follows the NCH < NH(3) <...

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Dades bibliogràfiques
Publicat a:J Phys Chem A
Autors principals: Wysokiński, Rafał, Zierkiewicz, Wiktor, Michalczyk, Mariusz, Scheiner, Steve
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2020
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7590972/
https://ncbi.nlm.nih.gov/pubmed/32052970
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpca.0c00257
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