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Activation of pentafluoropropane isomers at a nanoscopic aluminum chlorofluoride: hydrodefluorination versus dehydrofluorination

The hydrofluorocarbon 245 isomers, 1,1,1,3,3-pentafluoropropane, 1,1,1,2,2- pentafluoropropane, and 1,1,1,2,3-pentafluoropropane (HFC-245fa, HFC-245cb, and HFC-245eb) were activated through C–F bond activations using aluminium chlorofluoride (ACF) as a catalyst. The addition of the hydrogen source E...

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Bibliografische gegevens
Gepubliceerd in:Beilstein J Org Chem
Hoofdauteurs: Kervarec, Maëva-Charlotte, Braun, Thomas, Ahrens, Mike, Kemnitz, Erhard
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: Beilstein-Institut 2020
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7590627/
https://ncbi.nlm.nih.gov/pubmed/33133293
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.16.213
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