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Pyrrolidinium-Based Cyanides: Unusual Architecture and Dielectric Switchability Triggered by Order–Disorder Process

[Image: see text] Two three-dimensional metal–organic compounds of the formula Pyr(2)KM(CN)(6), where M = Co, Fe and Pyr = pyrrolidinium ((CH(2))(4)NH(2)(+)), have been found to crystallize at room temperature in a monoclinic structure, space group P2(1)/c. They are cyano-bridged compounds with an u...

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Detalhes bibliográficos
Publicado no:Inorg Chem
Main Authors: Trzebiatowska, Monika, Mączka, Mirosław, Gagor, Anna, Sieradzki, Adam
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2020
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7588038/
https://ncbi.nlm.nih.gov/pubmed/32551544
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.0c00637
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