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Crystal Structure and Physical Properties of the Cage Compound Hf(2)B(2–2δ)Ir(5+δ)
[Image: see text] Hf(2)B(2–2δ)Ir(5+δ) crystallizes with a new type of structure: space group Pbam, a = 5.6300(3) Å, b = 11.2599(5) Å, and c = 3.8328(2) Å. Nearly 5% of the boron pairs are randomly replaced by single iridium atoms (Ir(5+δ)B(2–2δ)). From an analysis of the chemical bonding, the crysta...
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| Publicado no: | Inorg Chem |
|---|---|
| Main Authors: | , , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical Society
2020
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7586331/ https://ncbi.nlm.nih.gov/pubmed/32946694 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.0c02073 |
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