The Chemistry of Acylgermanes: Triacylgermenolates Represent Valuable Building Blocks for the Synthesis of a Variety of Germanium-Based Photoinitiators

[Image: see text] The formation of a stable triacylgermenolate 2 as a decisive intermediate was achieved by using three pathways. The first two methods involve the reaction of KOtBu or alternatively potassium with tetraacylgermane 1 yielding 2 via one electron transfer. The mechanism involves the fo...

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Detalhes bibliográficos
Publicado no:Inorg Chem
Main Authors: Frühwirt, Philipp, Knoechl, Andreas, Pillinger, Michael, Müller, Stefanie M., Wasdin, Perry T., Fischer, Roland C., Radebner, Judith, Torvisco, Ana, Moszner, Norbert, Kelterer, Anne-Marie, Griesser, Thomas, Gescheidt, Georg, Haas, Michael
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2020
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7581296/
https://ncbi.nlm.nih.gov/pubmed/32993291
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.0c02181
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