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Topotactic Oxidation of Perovskites to Novel SrMo(1-x)M(x)O(4−δ) (M = Fe and Cr) Deficient Scheelite-Type Oxides

New polycrystalline SrMo(1−x)M(x)O(4−δ) (M = Fe and Cr) scheelite oxides have been prepared by topotactical oxidation, by annealing in air at 500 °C, from precursor perovskites with the stoichiometry SrMo(1−x)M(x)O(3−δ) (M = Fe and Cr). An excellent reversibility between the oxidized Sr(Mo,M)O(4−δ)...

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Détails bibliographiques
Publié dans:Materials (Basel)
Auteurs principaux: Cascos, V., Martínez-Coronado, R., Fernández-Díaz, M. T., Alonso, J. A.
Format: Artigo
Langue:Inglês
Publié: MDPI 2020
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7578960/
https://ncbi.nlm.nih.gov/pubmed/33036294
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/ma13194441
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