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Acyclic Cucurbit[n]uril-Type Receptors: Optimization of Electrostatic Interactions for Dicationic Guests
The synthesis of acyclic CB[n]-type host (1) is reported. By optimizing the placement of the sulfate groups nearby the electrostatically negative ureidyl C=O portals, the binding affinity of this class of receptors toward hydrophobic (di)ammonium guest molecules (5 – 23) is maximized. The x-ray crys...
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| 發表在: | Org Lett |
|---|---|
| Main Authors: | , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2020
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7576436/ https://ncbi.nlm.nih.gov/pubmed/32520574 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c01637 |
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