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Evaluating Metal Ion Identity on Catalytic Silylation of Dinitrogen Using a Series of Trimetallic Complexes
We report catalytic silylation of dinitrogen to tris(trimethylsilyl)amine by a series of trinuclear first row transition metal complexes (M = Cr, Mn, Fe, Co, Ni) housed in our tris(β-diketiminate) cyclophane (L(3-)). Yields are expectedly dependent on metal ion type ranging from 14 to 199 equiv NH(4...
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| Publié dans: | Eur J Inorg Chem |
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| Auteurs principaux: | , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2020
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7566828/ https://ncbi.nlm.nih.gov/pubmed/33071629 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.201901335 |
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